萘，又稱并萘，是種無(wú)色有光澤的片狀結(jié)晶。不溶于水，易升華，能隨水蒸氣揮發(fā)，有特殊氣味。是工業(yè)上重要的稠環(huán)芳烴，可用于生產(chǎn)苯酐、染料的中間體、橡膠助劑和殺蟲(chóng)劑。根據(jù)純度不同，萘可分為工業(yè)萘和精萘。那么焦油萘與石油萘怎么產(chǎn)生的呢？下面精萘廠家為你分析：

Naphthalene, also known as naphthalene, is a colorless and shiny flake crystal. It is insoluble in water, easy to sublimate, can volatilize with water vapor, and has a special smell. It is an important polycyclic aromatic hydrocarbon in industry and can be used to produce phthalic anhydride, intermediate of dyes, rubber auxiliaries and pesticides. According to the purity, naphthalene can be divided into industrial naphthalene and refined naphthalene. How did tar naphthalene and petroleum naphthalene come into being? The following refined naphthalene manufacturer will analyze for you:

焦油萘

Tar naphthalene

從煤焦油中分離出來(lái)的萘稱之為焦油萘。在高溫煤焦油中萘約占8-12%。從焦油精餾塔側(cè)線切取出溫度區(qū)間為210-230℃的萘油餾分，經(jīng)過(guò)洗滌脫酚，再精餾分離輕組分，便可得到凝固點(diǎn)為78℃、純度為96%的工業(yè)萘。

Naphthalene separated from coal tar is called tar naphthalene. In high-temperature coal tar, naphthalene accounts for about 8-12%. Naphthalene oil fraction with a temperature range of 210-230 ℃ is cut from the side line of the tar distillation tower, washed and dephenolized, and then distilled to separate the light components to obtain industrial naphthalene with a freezing point of 78 ℃ and a purity of 96%.

工業(yè)萘中含雜質(zhì)硫茚（1-3%）、甲基萘（1-2%）及少量茚、焦油堿和焦油酸，經(jīng)過(guò)進(jìn)步酸洗和蒸餾，可得到硫含量小于0.1%、凝固點(diǎn)為79℃的精萘。若需要進(jìn)步精制使硫含量低于0.05%，則需采用加氫精制工藝。

Industrial naphthalene contains impurities such as indene (1-3%), methyl naphthalene (1-2%) and a small amount of indene, tar base and tar acid. After progressive acid washing and distillation, refined naphthalene with sulfur content less than 0.1% and freezing point of 79 ℃ can be obtained. If it is necessary to improve refining to make the sulfur content lower than 0.05%, the hydrofining process shall be adopted.

用工業(yè)萘小批量生產(chǎn)精萘的流程如下：將硫酸加入熔融的萘中脫水，攪拌后靜置分離廢酸。再加入98%的硫酸，在85-95℃條件下攪拌40分鐘，靜置分離廢酸。在攪拌下加入37%的甲醛溶液在85-95℃條件下攪拌50分鐘，加溫水?dāng)嚢韬箪o置，分層聚合物及磺化物料。用10%氫氧化鈉溶液中和PH到7-8，靜置后除去廢堿。后蒸餾冷卻可得到精萘產(chǎn)品。

The process of small batch production of refined naphthalene from industrial naphthalene is as follows: add sulfuric acid into molten naphthalene for dehydration, stir and then stand still to separate the waste acid. Then add 98% sulfuric acid, stir at 85-95 ℃ for 40 minutes, and stand still to separate the waste acid. Add 37% formaldehyde solution under stirring and stir for 50 minutes at 85-95 ℃. Stir with warm water and then stand still. Layer the polymer and sulfonated material. Neutralize PH to 7-8 with 10% sodium hydroxide solution, and remove waste alkali after standing. After distillation and cooling, refined naphthalene products can be obtained.

石油萘

Petroleum naphthalene

石油萘的原料來(lái)自于催化重整、催化裂化和烴類裂解等過(guò)程的重芳烴組分。在催化重整油中，甲基萘的含量約為55%。先經(jīng)過(guò)萃取和吸附，從原料餾分中分離出萘的各種同系物，然后采用催化臨氫脫烷基的方法，以Cr2O3-Al2O3為催化劑，在400-800℃和0.5-7兆帕下進(jìn)行臨氫脫甲基反應(yīng)，反應(yīng)產(chǎn)物經(jīng)冷卻氣相物質(zhì)后，蒸餾除去輕組分苯、甲苯、二甲苯等，后進(jìn)步精餾可得到石油萘產(chǎn)品。產(chǎn)品用溶劑吸收和溶劑洗滌的方法進(jìn)行提純，純度可達(dá)99.73%。

The raw material of petroleum naphthalene comes from the heavy aromatics components in catalytic reforming, catalytic cracking and hydrocarbon cracking. In the catalytic reforming oil, the content of methyl naphthalene is about 55%. After extraction and adsorption, various homologues of naphthalene are separated from the raw material fraction, and then the method of catalytic hydrodealkylation is adopted. With Cr2O3-Al2O3 as catalyst, the hydrodemethylation reaction is carried out at 400-800 ℃ and 0.5-7 MPa. After the reaction product is cooled by gas phase substances, the light components of benzene, toluene, xylene, etc. are removed by distillation, and then the petroleum naphthalene product can be obtained by further distillation. The product is purified by solvent absorption and solvent washing, and the purity can reach 99.73%.

據(jù)估計(jì)，以輕柴油為裂解原料的年產(chǎn)30萬(wàn)噸的乙烯裝置，，可副產(chǎn)焦油9萬(wàn)噸，其中萘和萘潛量為4-5萬(wàn)噸。

It is estimated that an ethylene plant with an annual output of 300000 tons using light diesel oil as cracking feedstock can produce 90000 tons of tar by side, of which naphthalene and naphthalene have a potential of 40000 to 50000 tons.

精萘可用染料，醫(yī)藥等域，如生產(chǎn)2-萘酚、1-萘酚和甲萘胺等，也是生產(chǎn)樟腦的主要原料。您的使用有需求就來(lái)我們網(wǎng)站咨詢，或者直接撥打我們電話http://baruria.com了解！

Refined naphthalene can be used in dye, medicine and other fields, such as production of 2-naphthol, 1-naphthol and methylnaphthylamine, and is also the main raw material for production of camphor. If you need to use it, please come to our website or call us directly http://baruria.com Understand!